- John C. Van Dyke, Author (1856–1932; member, 1897–1932)
- Paul van Dyke, Professor of Modern History (1859–1933; member, 1900–1933)
- Tertius Van Dyke, Clergyman (1886–1958; member, 1920–1958)
- Kruseman van Elten, Painter (1829–1904; member, 1889–1896)
- J. C. Van Eyk, Lawyer (1853–after 1901; member, 1895–1898)
- William C. Van Horne, Railroad President (1843–1915; member, 1904–1915)
- David Van Nostrand, Publisher (1811–1886; member, 1863–1886)
- John V. Van Pelt, Architect (1874–1962; member, 1909–1962)
- James T. Van Rensselaer, Lawyer/Politician (1842–1899; member, 1871–1876)
- Alfred Van Santvoord, Shipbuilder (1819–1901; member, 1877–1901)
- John Van Schaick Jr., Clergyman (1873–1949; member, 1918–1949)
- Stephen W. Van Schaick, Artist (1847–1920; member, 1892–1901)
- Howard Van Sinderen, Lawyer (1860–1933; member, 1909–1933)
- Frederick B. Van Vorst, Lawyer (1855–1919; member, 1882–1919)
- Hooper C. Van Vorst, Lawyer/Judge (1817–1889; member, 1859–1889)
- Bleecker Van Wagenen, Publisher (1847–1921; member, 1908–1921)
- G. G. Van Wagenen, Lawyer/Trustee (1800–1858; member, 1856–1858)
- Ames Van Wart, Sculptor (1841–1927; member, 1870–1927)
- E. B. Van Winkle, Civil Engineer (1842–1920; member, 1870–1920)
- Edgar S. Van Winkle, Lawyer (1810–1882; member, 1847–1882)
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