- Frederick Kammerer, Physician (1856–1928; member, 1894–1928)
- Robert P. Kane, Lawyer (1827–1906; member, 1859–1860s)
- Edwin B. Katte, Engineer (1871–1928; member, 1917–1928)
- J. Murray Kay, Publisher (1842–1915; member, 1899–1915)
- William A. Keener, Dean, Columbia College Law School (1856–1913; member, 1894–1913)
- C. M. Keller, Lawyer (1810–1874; member, 1869–1874)
- James Edward Kelley, Banker (1827–1892; member, 1859–1865)
- Nicholas Kelley, Lawyer (1885–1965; member, 1922–1965)
- Vernon Lyman Kellogg, Scientist (1867–1937; member, 1920–1933)
- Edmond Kelly, Lawyer (1851–1909; member, 1892–1909)
- Robert Kelly, Merchant (Dry Goods)/Public Servant (1808–1856; member, 1847–1856)
- Robert Kelly, Lawyer/Manufacturer (Iron/Copper) (1848–1916; member, 1875–1889)
- John Kelman, Clergyman (1864–1929; member, 1921–1923)
- Carl Kelsey, Professor of Sociology (1870–1953; member, 1912–1953)
- Gouverneur Kemble, Manufacturer (West Point Foundry)/Congressman (1786–1875; member, 1847–1875)
- Peter Kemble, Manufacturer (West Point Foundry) (1825–1887; member, 1847–1855)
- Peter Kemble, Artist (1857–1900; member, 1889–1900)
- William Kemble, Manufacturer (West Point Foundry) (1795–1881; member, 1847–1881)
- James Furman Kemp, Professor of Geology (1859–1926; member, 1900–1926)
- Edward H. Kendall, Architect (1842–1901; member, 1883–1901)
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