- Christian H. Schultz, Merchant (1829–1891; member, 1889–1891)
- George W. Schurman, Lawyer (1867–1931; member, 1917–1931)
- Jacob G. Schurman, President, Cornell University/U.S. Ambassador to Germany (1854–1942; member, 1903–1942)
- Carl Schurz, Statesman (1829–1906; member, 1892–1906)
- Carl L. Schurz, Lawyer (1871–1924; member, 1912–1924)
- George L. Schuyler, Steamboat Line Owner/Yachtsman (1811–1890; member, 1876–1887)
- Montgomery Schuyler, Journalist (1843–1914; member, 1885–1914)
- Montgomery Schuyler, Diplomatic Officer (1877–1955; member, 1910–1955)
- Montgomery Roosevelt Schuyler, Sportsman/Importer of Spirits (1845–1924; member, 1880–1924)
- Philip Schuyler, Army Officer/Civic Affairs (1836–1906; member, 1873–1906)
- Robert Livingston Schuyler, Professor of History (1883–1966; member, 1922–1966)
- Benjamin William Schwab, Importer, North German Lloyds (1867–1899; member, 1899–1899)
- Gustav Schwab, Merchant (1822–1888; member, 1880–1888)
- Gustav H. Schwab, Shipping/Civic Affairs (1851–1912; member, 1884–1912)
- Hermann C. Schwab, Merchant (1853–1898; member, 1894–1898)
- John C. Schwab, Professor (1865–1916; member, 1892–1916)
- L. Henry Schwab, Clergyman (1857–1911; member, 1901–1911)
- Clinton Scollard, Author (1860–1932; member, 1904–1932)
- Francis M. Scott, Judge (1848–1922; member, 1890–1922)
- Frank H. Scott, Publisher (1848–1912; member, 1893–1912)
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