- Charles Knapp, Banker/Congressman (1797–1880; member, 1863–1874)
- Shepherd Knapp, Banker (1795–1875; member, 1847–1850)
- Charles Kneeland, Merchant (Cotton) (1808–1881; member, 1853–1856)
- Charles Kneeland Jr., Merchant (Cotton)/Railroad Official (1830–1866; member, 1865–1866)
- Edward Knoblock, Playwright (1874–1945; member, 1913–1945)
- Michael Knoedler, Art Dealer (1823–1878; member, 1864–1878)
- Benjamin Knower, Railroad Official (1839–1902; member, 1866–1902)
- Theodore Ely Knowlton, Engineer (1872–1953; member, 1920–1953)
- George William Knox, Professor, Union Theological Seminary (1853–1912; member, 1900–1912)
- Henry Hobart Knox, Mining Engineer (1865–1954; member, 1908–1954)
- John J. Knox, Banker/Public Servant (1828–1892; member, 1886–1892)
- Herman H. Kohlsaat, Editor (1853–1924; member, 1922–1924)
- Francis Korbay, Musician (1846–1913; member, 1892–1913)
- Frederick W. Kost, Artist (1861–1923; member, 1905–1923)
- Alvin W. Krech, Banker (1858–1928; member, 1900–1928)
- Kyo Kumasaki, Japanese Consul General (c. March 1887–1923; member, 1922–1923)
- Edward J. Kuntze, Sculptor (c. 1826–1870; member, 1864–1870)
- George F. Kunz, Mineralogist (1856–1932; member, 1895–1932)
- Bancel La Farge, Artist (1865–1938; member, 1894–1938)
- C. Grant La Farge, Architect (1862–1938; member, 1892–1938)
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