- Gouverneur Kemble, Manufacturer (West Point Foundry)/Congressman (1786–1875; member, 1847–1875)
- Peter Kemble, Manufacturer (West Point Foundry) (1825–1887; member, 1847–1855)
- Peter Kemble, Artist (1857–1900; member, 1889–1900)
- William Kemble, Manufacturer (West Point Foundry) (1795–1881; member, 1847–1881)
- James Furman Kemp, Professor of Geology (1859–1926; member, 1900–1926)
- Edward H. Kendall, Architect (1842–1901; member, 1883–1901)
- William Mitchell Kendall, Architect (1856–1941; member, 1894–1941)
- William Sergeant Kendall, Artist (1869–1938; member, 1910–1938)
- Henry L. Kendrick, Army Officer/Professor (1811–1891; member, 1868–1891)
- Thomas W. Kennard, Railroad Engineer (1825–1893; member, 1863–1869)
- Edward G. Kennedy, Merchant/Amateur (1849–1932; member, 1918–1932)
- Foster Kennedy, Physician (1884–1952; member, 1916–1952)
- James L. Kennedy, Lawyer/Philanthropist (c. 1823–1865; member, 1860–1861)
- John S. Kennedy, Financier/Philanthropist (1830–1909; member, 1863–1909)
- John Frederick Kensett, Artist (1816–1872; member, 1849–1872)
- Henry W. Kent, Librarian, Grolier Club (1866–1948; member, 1904–1948)
- James Kent, Army Officer/Author (1830–1886; member, 1873–1886)
- William Kent, Judge (1802–1861; member, 1856–1850s)
- David Keppel, Print Dealer (1877–1956; member, 1918–1934)
- Frederick Paul Keppel, Dean, Columbia College (1875–1943; member, 1911–1943)
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